Jan
9
elenacondriuc asked:
A chemical engineer studying the properties of fuels placed in 1.500 g of a hydrocarbon in the bomb of a calorimeter, and filled it with O2 gas. The bomb was immersed in 2.500 L of water and the reaction initiated. The water temperature rose from 20.00 C to 23.55 C. If the calotimeter (excluding the water) had a heat capacity of 403 J/K, What is the heat of combustion (qv) per gram of the fuel?
JAE
A chemical engineer studying the properties of fuels placed in 1.500 g of a hydrocarbon in the bomb of a calorimeter, and filled it with O2 gas. The bomb was immersed in 2.500 L of water and the reaction initiated. The water temperature rose from 20.00 C to 23.55 C. If the calotimeter (excluding the water) had a heat capacity of 403 J/K, What is the heat of combustion (qv) per gram of the fuel?
JAE
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SCOT
Since the temperature is increases , the combustion of the fuel is must be exothermic so the enthalpy must be negative.
Increase temperature = 296.55 K – 293 K = 3.55 K
Heat evolved by reaction
= heat absorb by the water
= heat capacity x increase temperature
= 403 J/K x 3.55 K
= 1430.65 J
Thus qv = ^H = - 1430.65 J
What is the heat of combustion (qv) per gram of the fuel?
= - 1430.65 J / 1.500 g
= -953.766 J/g
Thus the heat combustion is -953.766 J per g of fuel.